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1 article(s) from LaMartina, Kelsey B

Selective benzylic C–H monooxygenation mediated by iodine oxides

Kelsey B. LaMartina,
Haley K. Kuck,
Linda S. Oglesbee,
Asma Al-Odaini and
Nicholas C. Boaz

Beilstein J. Org. Chem. 2019, 15, 602–609, doi:10.3762/bjoc.15.55

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Figure 1: Catalyst optimization for the monooxidation of n-butylbenzene mediated by the iodate anion.

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Figure 2: NHPI-catalyzed oxidation of secondary benzylic C–H bonds mediated by iodine(V). ^a100 °C for 18 h; ^b...

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Figure 3: NHPI-catalyzed oxidation of di-benzylic C–H bonds mediated by iodate.

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Figure 4: NHPI-catalyzed oxidation of substrates containing primary and tertiary benzylic C–H bonds. ^aReactio...

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Figure 5: Competitive deuterium KIE for the oxidation of ethyl benzene by the NHPI-iodate system.

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Figure 6: Pyrolysis of an acyl perester in the presence of molecular iodine.

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Figure 7: Proposed mechanism for the selective monooxygenation of benzylic C–H bonds.

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Published 05 Mar 2019

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